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Monomer consumption rates during gelation at various temperatures: A fast transient fluorescence study

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dc.contributor.authorPekcan, Ö.
dc.contributor.authorKaya, D.
dc.date.accessioned2026-01-25T23:43:30Z
dc.date.issued2001-07-09
dc.description.abstractAbstractThe gelation during free‐radical crosslinking copolymerization (FCC) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDM) was studied by using fast transient fluorescence (FTRF) technique. Pyrene (Py) was used as a probe for the FTRF experiments. Fluorescence lifetimes of Py from its decay traces were measured and used to monitor the gelation process at various temperatures. MMA consumption rates were measured during gelation process by using the Stern–Volmer model. Gelation activation energy ΔEG was measured and found to be 15.6 kcal mol−1. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 3161–3168, 2001
dc.description.urihttps://doi.org/10.1002/app.1768
dc.description.urihttps://dx.doi.org/10.1002/app.1768
dc.identifier.doi10.1002/app.1768
dc.identifier.eissn1097-4628
dc.identifier.endpage3168
dc.identifier.issn0021-8995
dc.identifier.openairedoi_dedup___::a492ed86aaae4a821f1268a64282ebaf
dc.identifier.orcid0000-0002-0082-8209
dc.identifier.startpage3161
dc.identifier.urihttps://hdl.handle.net/11527/53036
dc.identifier.volume81
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofJournal of Applied Polymer Science
dc.rightsCLOSED
dc.titleMonomer consumption rates during gelation at various temperatures: A fast transient fluorescence study
dc.typeArticle
dspace.entity.typePublication

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