Yayın:
Preparation of azo functional poly(isobutyl vinyl ether) oligomers and block copolymers via combination of living cationic and condensation polymerization

dc.contributor.authorTunca, Umit
dc.contributor.ituauthorTunca, Ümit
dc.date.accessioned2026-01-25T01:55:17Z
dc.date.issued1995-01-01
dc.description.abstractAbstract This paper reports the synthesis and characterization of azo functional poly(isobutyl vinyl ether) oligomers and block copolymers containing poly(isobutyl vinyl ether) and oligoesterdiol segments. Isobutyl vinyl ether was polymerized using a trifluoromethanesulfonic acid/tetrahydrothiophene initiating system in dichloromethane at −30°C, and quantitatively terminated with labile azo compounds to give poly(isobutyl vinyl ether) with well-defined molecular weight and end-groups. Also, diblock copolymers with poly(isobutyl vinyl ether) and oligoesterdiol segments were synthesized by termination of living, cationically polymerized isobutyl vinyl ether with oligoesterdiol.
dc.description.urihttps://doi.org/10.1016/0032-3861(95)99791-r
dc.description.urihttps://dx.doi.org/10.1016/0032-3861(95)99791-r
dc.identifier.doi10.1016/0032-3861(95)99791-r
dc.identifier.endpage3961
dc.identifier.issn0032-3861
dc.identifier.openairedoi_dedup___::480cc930527c69daf8e876a26876802f
dc.identifier.orcid0000-0001-8767-6166
dc.identifier.startpage3955
dc.identifier.urihttps://hdl.handle.net/11527/42047
dc.identifier.volume36
dc.language.isoeng
dc.publisherElsevier BV
dc.relation.ispartofPolymer
dc.rightsCLOSED
dc.titlePreparation of azo functional poly(isobutyl vinyl ether) oligomers and block copolymers via combination of living cationic and condensation polymerization
dc.typeArticle
dspace.entity.typePublication
person.identifier.orcid0000-0001-8767-6166

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