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Polymers with acyloxime ester in the main chain: Synthesis, characterization and initiator properties of an azo‐containing ester initiator

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dc.contributor.authorOnen, Aysen
dc.contributor.authorDenizligil, Selcuk
dc.contributor.authorYagci, Yusuf
dc.date.accessioned2026-01-26T06:36:35Z
dc.date.issued1994-04-01
dc.description.abstractAbstractFor application as initiator, a new polymeric azo‐acyloxime ester (AOE) was synthesized by condensation of 4,4′‐azobis(4‐cyanopentanoic acid chloride) (ACPC) with 1‐(4‐hydroxyphenyl)‐1,2‐propanedione‐2‐oxime (HPO). The initiator structure was confirmed by IR and NMR spectroscopy. The kinetics of the free‐radical polymerization of styrene initiated by AOE was investigated and the kinetic parameters evaluated. The initiation of polymerization of styrene by means of AOE yields polymers with photoactive acyloxime groups in the main chain.
dc.description.urihttps://doi.org/10.1002/apmc.1994.052170109
dc.description.urihttps://dx.doi.org/10.1002/apmc.1994.052170109
dc.identifier.doi10.1002/apmc.1994.052170109
dc.identifier.eissn1522-9505
dc.identifier.endpage89
dc.identifier.issn0003-3146
dc.identifier.openairedoi_dedup___::ef3c24b640134d633a9675674be14180
dc.identifier.orcid0000-0002-7169-608x
dc.identifier.startpage79
dc.identifier.urihttps://hdl.handle.net/11527/62780
dc.identifier.volume217
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofDie Angewandte Makromolekulare Chemie
dc.rightsCLOSED
dc.titlePolymers with acyloxime ester in the main chain: Synthesis, characterization and initiator properties of an azo‐containing ester initiator
dc.typeArticle
dspace.entity.typePublication

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