Fabrication of Fe/Bi bimetallic magnetic nano-oxides (IBBMNOs) as efficient remediator for hexavalent chromium from aqueous environment

Abstract

In this study, highly efficient Fe/Bi bimetallic magnetic nanooxides (IBBMNOs) were used as adsorbent for the removal of Cr(VI) from an aqueous environment. The IBBMNOs were synthesized by a simple and facile chemical reduction method. After that, different analytical techniques were used to characterize the resultant nanomaterial. According to characterization results, the IBBMNOs are highly porous look like cotton beads with an average size of 60-69 nm. BET results show that IBBMNOs are highly porous with a high surface area. After optimizing different parameters such as pH, adsorbent dose, and time study, an excellent adsorption capacity was achieved up to 185 mg/g in 10 min. The calculated data of the adsorption process was well fitted with Langmuir and pseudo-first-order kinetic model. The prepared materials have good usability as compared to reported adsorbent materials can be used for five different cycles with good removal efficiency of chromium ion from aqueous samples. Schematic illustration of adsorption of Cr(VI) from aqueous solution by IBBMNOs.