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Allyloxy isoquinolinium salts as initiators for cationic polymerization

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dc.contributor.authorAtmaca, Levent
dc.contributor.authorOnen, Aysen
dc.contributor.authorYagci, Yusuf
dc.date.accessioned2026-01-24T17:56:03Z
dc.date.issued2001-04-01
dc.description.abstractAbstract 2-Propenyloxy isoquinolinium hexafluoroantimonate and 2-methyl-2-propenyloxy isoquinolinium hexafluoroantimonate were synthesized and characterized. Their capability to act as initiator and co-initiator for the cationic polymerization of cyclohexene oxide (CHO) was examined. Both thermally and photochemically latent effectiveness of these salts in promoting polymerization of CHO at 70°C and λ=350 nm, respectively was investigated. The accelearating effect of thermal and photochemical radical sources were also demonstrated. The contribution of electron transfer and addition–fragmentation mechanisms was discussed.
dc.description.urihttps://doi.org/10.1016/s0014-3057(00)00160-9
dc.description.urihttps://dx.doi.org/10.1016/s0014-3057(00)00160-9
dc.identifier.doi10.1016/s0014-3057(00)00160-9
dc.identifier.endpage682
dc.identifier.issn0014-3057
dc.identifier.openairedoi_dedup___::1e258bd07bfe3e50d3a4403f00d4eee4
dc.identifier.orcid0000-0002-7169-608x
dc.identifier.startpage677
dc.identifier.urihttps://hdl.handle.net/11527/36717
dc.identifier.volume37
dc.language.isoeng
dc.publisherElsevier BV
dc.relation.ispartofEuropean Polymer Journal
dc.rightsCLOSED
dc.titleAllyloxy isoquinolinium salts as initiators for cationic polymerization
dc.typeArticle
dspace.entity.typePublication

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