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Star polymers with POSS via azide–alkyne click reaction

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dc.contributor.authorGungor, Eda
dc.contributor.authorBilir, Cigdem
dc.contributor.authorDurmaz, Hakan
dc.contributor.authorHizal, Gurkan
dc.contributor.authorTunca, Umit
dc.contributor.ituauthorDurmaz, Hakan
dc.contributor.ituauthorTunca, Ümit
dc.date.accessioned2026-01-25T02:01:03Z
dc.date.issued2009-10-06
dc.description.abstractAbstractAzidopropyl‐heptaisobutyl‐substituted polyhedral oligomeric silsesquioxane (POSS‐N3) was reacted with 1,1,1‐tris[4‐(2‐propynyloxy)phenyl]‐ethane (1) and poly(ethylene glycol) (PEG)‐b‐poly(methyl methacrylate) (PMMA) copolymer with alkyne at its center (PEG‐PMMA‐alkyne) affording the first time synthesis of 3‐arm star POSS and PEG‐PMMA‐POSS 3‐miktoarm star terpolymer, respectively, in the presence of CuBr/N,N,N′,N″,N″‐pentamethyldiethylenetriamine as catalyst and N,N‐dimethylformamide/tetrahydrofuran as solvent at room temperature. The precursors and the target star polymers were characterized comprehensively by 1H NMR, GPC, and DSC. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 5947–5953, 2009
dc.description.urihttps://doi.org/10.1002/pola.23637
dc.description.urihttps://dx.doi.org/10.1002/pola.23637
dc.identifier.doi10.1002/pola.23637
dc.identifier.eissn1099-0518
dc.identifier.endpage5953
dc.identifier.issn0887-624X
dc.identifier.openairedoi_dedup___::4962832e3c66f83d9932f2c559ca13b0
dc.identifier.orcid0000-0003-4710-2496
dc.identifier.orcid0000-0001-8767-6166
dc.identifier.startpage5947
dc.identifier.urihttps://hdl.handle.net/11527/42213
dc.identifier.volume47
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofJournal of Polymer Science Part A: Polymer Chemistry
dc.rightsCLOSED
dc.titleStar polymers with POSS via azide–alkyne click reaction
dc.typeArticle
dspace.entity.typePublication
person.identifier.orcid0000-0003-4710-2496
person.identifier.orcid0000-0001-8767-6166

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