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Synthesis and Properties of Copper(II) Phthalocyanines with Monoazacrown and Crown Ethers as Peripheral Substituents

dc.contributor.authorKandaz, Mehmet
dc.contributor.authorBekaroğlu, Özer
dc.date.accessioned2026-01-24T22:52:52Z
dc.date.issued1999-06-01
dc.description.abstractSoluble and less soluble phthalocyaninatocopper(II) derivatives (4a and 4b) were prepared from the corresponding 7-[(4′-benzo-15-crown-5)oyl]-15, 16-dibromo-2,3,6,7,8,9,11,12-octahydro-5H-benzo[e]-[1,4,10,13,7] tetraoxaazacyclopentadecine (3a) and 7-(2′-tosylaminoethyl)-15, 16-dibromo-2,3,6,7,8,9,11, 12-octahydro-5H-benzo[e]-[1,4,10,13,7] tetraoxaazacyclopentadecine (3b) and CuCN in pyridine. A less soluble novel multifunctionalized scorpiand macrocycle-substituted phthalocyanine (4c) in which an NH2CH2CH2— chain is appended to a monoazacrown ether ring was obtained by detosylation of 4b with concentrated sulfuric acid.
dc.description.urihttps://doi.org/10.1002/(sici)1099-1409(199906)3:5<339::aid-jpp143>3.0.co;2-n
dc.description.urihttps://dx.doi.org/10.1002/(sici)1099-1409(199906)3:5<339::aid-jpp143>3.0.co;2-n
dc.identifier.doi10.1002/(sici)1099-1409(199906)3:5<339::aid-jpp143>3.0.co;2-n
dc.identifier.eissn1099-1409
dc.identifier.endpage345
dc.identifier.issn1088-4246
dc.identifier.openairedoi_dedup___::3179c50ed8a27d971d6897ea49863162
dc.identifier.orcid0000-0001-7904-5735
dc.identifier.startpage339
dc.identifier.urihttps://hdl.handle.net/11527/39100
dc.identifier.volume03
dc.language.isoeng
dc.publisherWorld Scientific Pub Co Pte Ltd
dc.relation.ispartofJournal of Porphyrins and Phthalocyanines
dc.sdg.typeGoal 3: Good Health and Well-being
dc.titleSynthesis and Properties of Copper(II) Phthalocyanines with Monoazacrown and Crown Ethers as Peripheral Substituents
dc.typeArticle
dspace.entity.typePublication

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