Publication: Pmdeta'nın Ligand Ve İndirgen Olarak Stirenin Aget Atrp methodunda Kullanımı
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Fen Bilimleri Enstitüsü
Institute of Science And Technology
Institute of Science And Technology
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Bu çalışmada; oldukça yaygın kullanım alanına sahip stiren monomerinin, homojen ve heterojen ortamlardaki faklılıklarını göstermek amacıyla, toluen ve dimetilformamid (DMF) içerisindeki, havada kararlı halde bulunan CuBr2 nin ve belirli oranlardaki CuBr2-CuBr karışımlarının katalizör, N,N,N′,N′′,N′′-pentametildietilentriaminin (PMDETA) hem ligand hem de indirgen ajan görevlerini yerine getirdiği AGET ATRP yönetmiyle polimerleşmesi detaylı bir şekilde incelenmiştir
In this study, AGET ATRP of styrene (St) in toluene and dimethylformamide (DMF) to compare low and high polar solvents (provide heterogeneous and homogeneous conditions, respectively) using air-stable CuBr2 and in the specified ratios CuBr2-CuBr mixtures as the catalyst and N,N,N′,N′′,N′′-pentamethyldiethylenetriamine (PMDETA) as both ligand and reducing agent were performed. AGET ATRP of styrene could been controlled well under heterogeneous and homogeneous conditions.
In this study, AGET ATRP of styrene (St) in toluene and dimethylformamide (DMF) to compare low and high polar solvents (provide heterogeneous and homogeneous conditions, respectively) using air-stable CuBr2 and in the specified ratios CuBr2-CuBr mixtures as the catalyst and N,N,N′,N′′,N′′-pentamethyldiethylenetriamine (PMDETA) as both ligand and reducing agent were performed. AGET ATRP of styrene could been controlled well under heterogeneous and homogeneous conditions.
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Tez (Yüksek Lisans) -- İstanbul Teknik Üniversitesi, Fen Bilimleri Enstitüsü, 2014
Thesis (M.Sc.) -- İstanbul Technical University, Institute of Science and Technology, 2014
Thesis (M.Sc.) -- İstanbul Technical University, Institute of Science and Technology, 2014
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Kontrollü/Yaşayan Radikal Polimerizasyon Teknikleri, Atom Transfer Radikal Polimerizasyonu, Controlled/Living Radical Polymerization, Atom Transfer Radical Polymerization
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