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In situsynthesis of A3-type star polymer/clay nanocomposites by atom transfer radical polymerization

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dc.contributor.authorAydin, Muhammed
dc.contributor.authorAtilla Tasdelen, Mehmet
dc.contributor.authorUyar, Tamer
dc.contributor.authorYagci, Yusuf
dc.date.accessioned2026-01-26T05:00:09Z
dc.date.issued2013-10-11
dc.description.abstractA series of A3-type star poly(methylmethacrylate)/ clay nanocomposites is prepared by in situ atom transfer radi- cal polymerization (ATRP) initiated from organomodified mont- morillonite containing quaternary trifunctional ATRP initiator. The first order kinetic plot shows a linear behavior, indicating the controlled character of the polymerization. The resulting nanocomposites are characterized by spectroscopic (XRD), thermal (DSC and TGA), and microscopic (TEM) analyses. The exfoliated nanocomposite has been obtained when polymeriza- tion was conducted with 1% of organic clay loading. Thermal analyses show that all nanocomposites have higher glass tran- sition values and thermal stabilities compared to neat polymer. V C 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 5257-5262
dc.description.urihttps://doi.org/10.1002/pola.26957
dc.description.urihttps://dx.doi.org/10.1002/pola.26957
dc.identifier.doi10.1002/pola.26957
dc.identifier.endpage5262
dc.identifier.issn0887-624X
dc.identifier.openairedoi_dedup___::e6c1b11aa68e67105ef195219da75f0b
dc.identifier.orcid0000-0002-3989-4481
dc.identifier.startpage5257
dc.identifier.urihttps://hdl.handle.net/11527/61625
dc.identifier.volume51
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofJournal of Polymer Science Part A: Polymer Chemistry
dc.rightsCLOSED
dc.titleIn situsynthesis of A3-type star polymer/clay nanocomposites by atom transfer radical polymerization
dc.typeArticle
dspace.entity.typePublication

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