The Synthesis of New Triazole‐Linked Supramolecules Based on Bis‐[1,3]‐Naphthodioxocines

Abstract

Abstract In this study, the synthesis of novel three molecular cages based on bis‐structure of 8,16‐methano‐16H‐dinaphtho[2,1‐d: 1’,2’‐g][1,3]dioxocine (DNDO) is reported. The linkers between bis‐DNDO structures are bearing both etheric structures and bis(1,2,3‐triazole) moieties that are acting also as coordination ligands. The cavities of the molecular cages change depending of the position of dioxocine ring oxygens.