Robust carbon quantum dots supported cobalt oxide composite particles prepared by hydrothermal process for green hydrogen generation via sodium borohydride hydrolysis

Abstract

Carbon quantum dots (CQDs), a new class of carbon nanostructures with a particle size of 10 nm, exhibit important properties such as easy surface functionalization, low cost, chemical inertness, water solubility and low toxicity. In this study, an effective catalyst was synthesized using cobalt oxide (Co3O4) metal nanoparticles dispersed on CQD support material obtained from sucrose by hydrothermal method (Co3O4-SCQD-HT). The resulting catalyst system was used for effective hydrogen (H2) production from sodium borohydride (NaBH4) hydrolysis. Hydrogen generation rate (HGR) values of 7041, 18,426 and 27,555 mlmin- 1gcat-1 were obtained with Co3O4-SCQD catalysts synthesized during the hydrothermal process with water, ethanol and methanol solvents, respectively. The HGR values of the catalysts obtained in ethanol and methanol medium provided an improvement of approximately 2.5 and 4 times, respectively, compared to the catalyst prepared in water medium. The activation energy for NaBH4 hydrolysis by Co3O4-SCQD-HT was 29.92 kJmol- 1. Transmission Electron Microscopy (TEM), Energy-dispersive X-ray spectroscopy (EDS), nitrogen adsorption/desorption, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), Inductively coupled plasma optical emission spectroscopy (ICP-OES) and X-ray photoelectron spectroscopy (XPS) analyses were used for the characterization study. The average particle size for the Co3O4-SCQD-HT nanocomposite is approximately 3.27 nm. The presence of carbon (C), oxygen(O), nitrogen (N) and cobalt (Co) atoms was confirmed by XPS and EDS analysis.Siirt University's Scientific Research Projects support unit (2022-SIUEFEB-010) supported a part of this study.Siirt University's Scientific Research Projects support unit [2022-SIUEFEB-010]