Publication:
Hydroxylation of pendant vinyl groups of poly(3‐hydroxy undec‐10‐enoate) in high yield

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dc.contributor.authorHazer, B.
dc.contributor.authorEroglu, Ms
dc.contributor.authorCaykara, T.
dc.contributor.authorOzturk, T.
dc.contributor.departmentKimya Bölümü
dc.contributor.ituauthorÖztürk, Turan
dc.date.accessioned2026-01-25T00:11:17Z
dc.date.issued2005-06-28
dc.description.abstractAbstractPoly(3‐hydroxy undec‐10‐enoate) (PHU) was synthesized by feeding Pseudomonas oleovarans with 10‐undecenoic acid and nearly 100% hydroxylation of double bonds of PHU was achieved by hydroboration–oxidation reaction using 9‐borobicyclononane. The disappearance of vinyl signals of PHU in proton and 13C NMR spectra was observed. Acetylation of hydroxylated PHU was conducted for molecular weight measurements. Molecular weight and polydispersity of hydroxylated PHU were found to be 10,000 and 1.23, respectively, while that of the originals was 32,000 and 2.42. Decomposition temperatures of original and hydroxylated PHU were 280 and 200°C, respectively. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2132–2139, 2005
dc.description.urihttps://doi.org/10.1002/app.21943
dc.description.urihttps://dx.doi.org/10.1002/app.21943
dc.description.urihttps://avesis.gazi.edu.tr/publication/details/51d3ba1b-2bb0-4f54-a252-1cd78a18bf98/oai
dc.description.urihttps://hdl.handle.net/20.500.12628/20537
dc.identifier.doi10.1002/app.21943
dc.identifier.eissn1097-4628
dc.identifier.endpage2139
dc.identifier.issn0021-8995
dc.identifier.openairedoi_dedup___::3c9cfed7e124329cc1d9338863404254
dc.identifier.orcid0000-0003-3777-5320
dc.identifier.startpage2132
dc.identifier.urihttps://hdl.handle.net/11527/40504
dc.identifier.volume97
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofJournal of Applied Polymer Science
dc.rightsCLOSED
dc.subjectnano-technology
dc.subjectnatural sciences
dc.subjectengineering and technology
dc.subjectchemical sciences
dc.titleHydroxylation of pendant vinyl groups of poly(3‐hydroxy undec‐10‐enoate) in high yield
dc.typeArticle
dspace.entity.typePublication
person.identifier.orcid0000-0003-3777-5320

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